219985-31-6Relevant articles and documents
Fluorous phosphines and phosphine oxides
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, (2008/06/13)
A method of increasing the fluorous nature of a compound includes the step of reacting the compound with or tagging the compound with at least one of a second compound having the formula: wherein R is an alkyl group or an aryl group, n is 1, 2 or 3 and Rs is a spacer group and Rf is a branched fluorous group. A chemical compound having the general formula: wherein n, Rs and Rf are defined above.
Palladium-catalyzed synthesis of aqueous, fluorous, and supercritical CO2-soluble phosphines
Chen, Weiping,Xu, Lijin,Xiao, Jianliang
, p. 2675 - 2677 (2007/10/03)
(Equation presented) A generic simple and economical route has been developed for the synthesis of phosphines soluble in aqueous, fluorous, and supercritical CO2 phases. The methodology is based on the palladium-catalyzed Heck olefination of ha