220070-69-9Relevant academic research and scientific papers
Kinetic studies of a fast, reversible alkene radical cation cyclization reaction
Horner, John H.,Newcomb, Martin
, p. 1609 - 1616 (2007/10/03)
The radical cation formed by mesylate heterolysis from the 1,1-dimethyl-7,7-diphenyl-2-mesyloxy-6-heptenyl radical was studied in several solvents. Computational results suggest that the initially formed acyclic radical cation is a resonance hybrid with p
Radical heterolysis reactions. Dynamics of formation, collapse, and solvation of ion pairs determined by a competition kinetic method
Horner, John H.,Lal, Mukul,Newcomb, Martin
, p. 5497 - 5500 (2007/10/03)
The kinetics of radical heterolysis reactions, including rate constants for radical cation-anion contact ion pair formation, collapse of the contact pair back to the parent radical, and separation of the contact pair to a solvent-separated ion pair or fre
