220108-58-7

Upstream product

• 56613-80-0 D-2-phenylglycinol 
• 256454-83-8 6-hydroxymethyl-pyridine-2-carboximidic acid methyl ester 
• 586-98-1 2-Hydroxymethylpyridine 
• 50501-38-7 6-(hydroxymethyl)pyridine-2-carbonitrile 
• 10242-36-1 2-(hydroxymethyl)pyridine 1-oxide 

Downstream Products

• 256454-85-0 4-Hydroxy-benzoic acid 6-((R)-4-phenyl-4,5-dihydro-oxazol-2-yl)-pyridin-2-ylmethyl ester 
• 256454-84-9 4-Methoxycarbonyloxy-benzoic acid 6-((R)-4-phenyl-4,5-dihydro-oxazol-2-yl)-pyridin-2-ylmethyl ester 

Relevant academic research and scientific papers

Enantioselective allylic alkylation using polymer-supported palladium catalysts

Chiral 2'-(4'',5''-dihydro-2''-oxazolyl)-6'-(1-hydroxyalkyl)pyridines were grafted via ester-linkages directly to cross-linked polystyrene and to polyethyleneglycol-containing resins TentaGel and ArgoGel functionalized with carboxylic acid groups or via s

Palladium-catalyzed allylic alkylation using pyridino-oxazolines and quinolino-oxazolines as ligands - Influence of steric factors

Four new chiral pyridino- and quinolino-oxazolines were subjected to the palladium-catalyzed alkylation of 1,3-diphenyl-2-propenyl acetate. The enantioselectivity varied (82-88% ee) with the steric properties of the ligands. The results are discussed in connection with results previously obtained using analogous ligands.