22018-26-4Relevant articles and documents
Bu4NI-catalyzed decarboxylative acyloxylation of an sp 3 C-H bond adjacent to a heteroatom with α-oxocarboxylic acids
Zhang, Shuai,Guo, Li-Na,Wang, Hua,Duan, Xin-Hua
supporting information, p. 4308 - 4311 (2013/08/23)
A novel metal-free decarboxylative acyloxylation of an sp3 C-H bond in formamides and ethers has been explored. A variety of N-acyloxymethylamides and α-acyloxy ethers could be easily synthesized by this method. Preliminary mechanistic studies have shown that the reaction proceeded via a radical process. The Royal Society of Chemistry 2013.