220185-40-0

Basic information

• Product Name: 1,3-BIS[BIS(3,5-DITRIFLUOROMETHYLPHENYL)PHOSPHINO]PROPANE
• Synonyms: 1,3-BIS[BIS(3,5-DITRIFLUOROMETHYLPHENYL)PHOSPHINO]PROPANE
• CAS NO: 220185-40-0
• Molecular Formula: C₃₅H₁₈F₂₄P₂
• Molecular Weight: 956.43
• Mol File: 220185-40-0.mol

Chemical Properties

• Boiling Point: 557.6±50.0 °C(Predicted)
• Appearance: /
• CAS DataBase Reference: 1,3-BIS[BIS(3,5-DITRIFLUOROMETHYLPHENYL)PHOSPHINO]PROPANE(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3-BIS[BIS(3,5-DITRIFLUOROMETHYLPHENYL)PHOSPHINO]PROPANE(220185-40-0)
• EPA Substance Registry System: 1,3-BIS[BIS(3,5-DITRIFLUOROMETHYLPHENYL)PHOSPHINO]PROPANE(220185-40-0)

Safety Data

• Hazardous Substances Data: 220185-40-0(Hazardous Substances Data)

Usage

Type of Compound

Chiral diphosphine ligand

Application

Asymmetric catalysis, particularly in transition metal-catalyzed reactions

Performance

Exceptional in various catalytic reactions

Reactions

Hydrogenation, cross-coupling, and C-H activation

Industry Usage

Pharmaceutical industry (synthesis of chiral drugs), production of agrochemicals and fine chemicals

Structure

Unique structure allows for efficient coordination with transition metals

Benefits

Improved catalytic activity and selectivity in a wide range of organic reactions

Upstream product

• 15979-14-3 bis[3,5-bis(trifluoromethyl) phenyl]phosphine oxide 
• 328-70-1 3,6-bis(trifluoromethyl)bromobenzene 
• 109-64-8 1,3-dibromo-propane 
• 166172-69-6 bis(3,5-bis(trifluoromethyl)phenyl)phosphine 

Downstream Products

• 609854-36-6 dichloro[1,3-bis[bis[3,5-bis(trifluoromethyl)phenyl]phosphino]propane]palladium(II) 

Relevant articles and documents

Rhodium catalyzed C-C bond cleavage/coupling of 2-(azetidin-3-ylidene)acetates and analogs

The C-C bond cleavage/coupling of 2-(azetidin-3-ylidene)acetates with aryl boronic acids catalyzed by a rhodium complex was studied with a "conjugate addition/β-C cleavage/protonation" strategy.