220214-17-5

Basic information

• Product Name: cis-disulfhydryl[bis(dicyclohexylphosphino)ethane]platinum(II)
• CAS NO: 220214-17-5
• Molecular Weight: 683.843
• Mol File: 220214-17-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: cis-disulfhydryl[bis(dicyclohexylphosphino)ethane]platinum(II)(CAS DataBase Reference)
• NIST Chemistry Reference: cis-disulfhydryl[bis(dicyclohexylphosphino)ethane]platinum(II)(220214-17-5)
• EPA Substance Registry System: cis-disulfhydryl[bis(dicyclohexylphosphino)ethane]platinum(II)(220214-17-5)

Safety Data

• Hazardous Substances Data: 220214-17-5(Hazardous Substances Data)

Upstream product

• 90667-70-2 dichloro{bis(dicyclohexylphosphino)ethane}platinum(II) 
• 111848-59-0 cis-chloro(methyl){bis(dicyclohexylphosphino)ethane}platinum(II) 
• 111848-50-1 cis-methylhydrido{bis(dicyclohexylphosphino)ethane}platinum(II) 
• 126949-41-5 [Pt((C₆H₁₁)2P)2C₂H₄(CH₃)2] 
• 220214-03-9 cis-sulfhydrylmethyl[bis(dicyclohexylphosphino)ethane]platinum(II) 
• 7783-06-4 hydrogen sulfide 

Relevant articles and documents

Insertion of Elemental Sulfur and SO2 into the Metal-Hydride and Metal-Carbon Bonds of Platinum Compounds

Elemental sulfur (S8) has been found to insert only one sulfur atom into the metal-hydride bonds of the platinum alkyl and aryl hydride complexes [(dcpe)PtRH] (dcpe = Cy2PC2H4-PCy2). Unlike the parent compounds, the S-inserted complexes do not undergo reductive elimination to form the corresponding alkane- or arenethiols. Methane is lost from the methyl sulfhydryl complex. Sulfur dioxide was also found to insert into a platinum-methyl bond to form the corresponding S-bound sulfinate, which upon reacting with mineral acids generates methylsulfinic acid.