220308-32-7Relevant academic research and scientific papers
Practical radical cyclisations leading to the construction of near-stereopure quaternary carbon stereogenic centres
McCague, Raymond,Pritchard, Robin G.,Stoodley, Richard J.,Williamson, Douglas S.
, p. 2691 - 2692 (1998)
The 2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl auxiliary is effective in directing bromopropargyloxy additions to the olefinic bonds of vinylogous esters/carbonates; in the presence of AIBN and 1-ethylpiperidinium hypophosphite, the adducts undergo highly stereoselective reductive radical cyclisations in which quaternary carbon stereogenic centres are generated.
