220314-70-5

Upstream product

• 7786-67-6 isopulegol 
• 220314-67-0 (1R,2S,5R)-5-methyl-2-(5-methyl-1-methylene-4-hexenyl)cyclohexanol 
• 870-63-3 prenyl bromide 
• 994-30-9 triethylsilyl chloride 
• 220314-69-2 (1S,2R,4R)-4-methyl-1-(5-methyl-1-methylene-4-hexenyl)-2-(triethylsilyloxy)cyclohexane 

Relevant academic research and scientific papers

Isopulegol as a model compound: Metalation and substitution of an allylic position in the presence of an unprotected hydroxy function

When treated with butyllithium and potassium tert-butoxide for 2 h at 0 °C in hexanes, the unsaturated monoterpenic alcohol isopulegol is simultaneously deprotonated at the hydroxy function and the allylic methyl group. The metaloxy allylmetal species thu