220351-85-9Relevant academic research and scientific papers
Stereoselective 1,4-phenyl migration from silicon to carbon in α-siloxy cyclic acetal systems: A concise synthesis of 1,2-cis-phenyl C-glycoside and enantioenriched silanol
Nakazaki, Atsuo,Usuki, Junji,Tomooka, Katsuhiko
, p. 2064 - 2068 (2008)
The treatment of O-glycoside with alcohol in the presence of montmorillonite K10 clay and 4-? MS yields the 1,4-aryl migration product with a 1,2-cis-phenyl C-glycoside scaffold and a chiral silyl moiety with high stereoselectivity.
Epothilon derivatives, method for the production and the use thereof as pharmaceuticals
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Page/Page column 70, (2010/10/19)
Disclosed are epothilone compounds of formula I, which are useful as pharmaceutical compounds for treating, for example, malignant tumors and chronic inflammatory diseases and are useful in anti-angiogenesis therapy.
