22050-80-2Relevant academic research and scientific papers
Novel generation of azomethine imines from α-silylnitrosamines by 1,4- silatropic shift and their cycloaddition
Washizuka, Ken-Ichi,Nagai, Keiko,Minakata, Satoshi,Ryu, Ilhyong,Komatsu, Mitsuo
, p. 8849 - 8853 (1999)
Novel and facile generation of azomethine imines from α- silylnitrosamines and subsequent cycloaddition with dipolarophiles leading to a variety of pyrazole derivatives have been developed. The key to the reaction is a 1,4-silatropic shift caused by stron
