220617-73-2

Upstream product

• 103516-12-7 (Z)-3-deoxy-3-C-[(hydroxymethyl)methylene]-1,2:5,6-di-O-isopropylidene-α-D-ribo-hexofuranose 
• 220617-60-7 (S)-6-[(3aR,5S,6S,6aR)-5-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-2,2-dimethyl-6-vinyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-yl]-cyclohex-2-enone 
• 220617-70-9 (2S,5S)-2-[(3aR,5S,6S,6aR)-5-((R)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-2,2-dimethyl-6-vinyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-yl]-5-vinyl-cyclohexanone 

Downstream Products

• 220617-76-5 (R)-1-[(3aR,5S,6S,6aR)-6-((1S,2S,4S)-2-Hydroxy-4-vinyl-cyclohexyl)-2,2-dimethyl-6-vinyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl]-ethane-1,2-diol 

Relevant academic research and scientific papers

A chiral cyclohex-2-enone carrying a hexofuranosyl substituent which directs highly stereoselective 1,4-conjugate additions

The reaction of (Z)-3-deoxy-3-C-[(hydroxymethyl)methylene]-1,2:5,6-di- O-isopropylidene-α-D-ribo-hexofuranose, prepared from D-glucose, with 1,1- dimethoxycyclohexane in the presence of propanoic acid at 135°C, then at 200°C, provided two Claisen rearrang