220645-07-8

Upstream product

• 220645-08-9 p=methylphenyl 2,3,6-tri-O-benzoyl-1-thio-β-D-glucopyranoside 
• 211678-08-9 p-methylphenyl 2,3,4,6-tetra-O-benzyl-1-thio-β-D-galactopyranoside 

Downstream Products

• 1381858-09-8 methyl (2,3,4,6-tetra-O-benzyl-α-D-galactopyranosyl)-(1->4)-2,3,6-tri-O-benzoyl-β-D-glucopyranosyl-(1->4)-2,3,6-tri-O-benzyl-α-D-glucopyranoside 

Relevant academic research and scientific papers

Bromodimethylsulfonium bromide-silver triflate: A new powerful promoter system for the activation of thioglycosides

Bromodimethylsulfonium bromide (BDMS) in combination with silver triflate provides a very efficient thiophilic promoter system, capable of activating both "disarmed" and "armed" thioglycosides for glycosidic bond formation. The usefulness of this new prom

N-(Phenylthio)-ε-caprolactam: A new promoter for the activation of thioglycosides

N-(Phenylthio)-ε-caprolactam (1) has been applied as a new promoter for the activation of thioglycosides. This proceeds by the reaction of 1 with trifluoromethansulfonic anhydride, which subsequently activates the thioglycoside for glycosidic bond formation. Notably, the reaction proceeds efficiently at room temperature and is adaptable to our reactivity-based one-pot oligosaccharide synthesis.

Efficient activation of thioglycosides with N-(p-methylphenylthio) - Caprolactam-TMSOTf

N-(p-Methylphenylthio) - caprolactam (1) in combination with trimethylsilyl trifluoromethanesulfonate (TMSOTf) provides an efficient thiophilic promoter system, capable of activating different thioglycosides. Both 'armed' and 'disarmed' thioglycosyl donor