220655-11-8

Basic information

• Product Name: 1-diazomethyl-2-isopropoxy-benzene
• Synonyms: 1-diazomethyl-2-isopropoxy-benzene
• CAS NO: 220655-11-8
• Molecular Weight: 176.218
• Mol File: 220655-11-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-diazomethyl-2-isopropoxy-benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-diazomethyl-2-isopropoxy-benzene(220655-11-8)
• EPA Substance Registry System: 1-diazomethyl-2-isopropoxy-benzene(220655-11-8)

Safety Data

• Hazardous Substances Data: 220655-11-8(Hazardous Substances Data)

Downstream Products

• 301224-40-8 Hoveyda-Grubbs catalyst second generation 
• 1097639-08-1 (2,6-(2,6-(i)Pr₂-C₆H₃N=CMe)2C₅H₃N)Fe(NHCHC₆H₄OCH(CH₃)2) 
• 1097639-07-0 (2,6-(2,6-(i)Pr₂-C₆H₃N=CMe)2C₅H₃N)Fe(NCC₆H₄OCH(CH₃)2) 

Relevant articles and documents

A recyclable Ru-based metathesis catalyst

A Ru carbene (8, Scheme 2) that contains an internal metal-oxygen chelate is an active metathesis catalyst and is readily obtained by the sequential treatment of Cl2Ru(PPh3)3 with (2-isopropoxyphenyl)- diazomethane and PCy3. This Ru-carbene complex offers excellent stability to air and moisture and can be recycled in high yield by silica gel column chromatography. The structures of this and related complexes have been unambiguously established by NMR and single-crystal X-ray diffraction studies.