220741-56-0Relevant articles and documents
Simple and efficient method for n-boc protection of amines using PEG-400 as a reaction medium under mild conditions
Zeng, Hongyao,Li, Yongjia,Shao, Huawu
, p. 25 - 32 (2012)
Simple and efficient method for N-Boc protection of amines using PEG-400 as an ecofriendly reaction medium at room temperature is described. Various aromatic, heteroaromatic, and aliphatic amines were converted to the corresponding N-tert-butyl-carbamates in good to excellent yields in short times.
Chemoselective conversion of azides to t-butyl carbamates and amines
Jung, Yeon Joo,Chang, Yu Mi,Lee, Ji Hee,Yoon, Cheol Min
, p. 8735 - 8739 (2007/10/03)
Azides were converted to the corresponding carbamates using a system of 20 mol% of decaborane (B10H14) and 20 weight% of 10% Pd/C in methanol in the presence of di-tert-butyl dicarbonate at rt in high yields and to the corresponding amines using a system of 10 mol% of decaborane and 20 weight% of 10% Pd/C in methanol in the absence of di-tert-butyl dicarbonate at rt in high yields.