220829-92-5Relevant academic research and scientific papers
[PPN][Fe3(CO)9(C≡CH)] and [Fe3(CO)9(C≡COTi(THF)4Cl)] from the reaction of low-valent titanium with [Fe3(CO)9(CCO)]2-
Eveland, Randal W.,Raymond, Casey C.,Shriver, Duward F.
, p. 534 - 539 (1999)
TiCl3(DME)1.5 (DME = 1,2-dimethoxyethane) and a Zn-Cu couple react with [PPN]2[Fe3-(CO)9(CCO)] to give the new compound [PPN][Fe3(CO)9(C≡CH)] (I) (70% yield), a known compound [Fe3(CO)10(CCH2)] (II) (9% yield), and another new compound [Fe3(CO)9(CCOTi-(THF)4Cl)] (III). Compound I was characterized by 1H and 13C NMR, IR, mass spectrometry, and X-ray crystallography. Compound III was characterized by IR, mass spectrometry, 13C NMR, and X-ray crystallography.
