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((C6H5)2PCH2)2CH2Pd(CH2Si(CH3)3)CNB(C6H5)3 is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

220857-24-9

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220857-24-9 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 220857-24-9 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 2,2,0,8,5 and 7 respectively; the second part has 2 digits, 2 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 220857-24:
(8*2)+(7*2)+(6*0)+(5*8)+(4*5)+(3*7)+(2*2)+(1*4)=119
119 % 10 = 9
So 220857-24-9 is a valid CAS Registry Number.

220857-24-9Downstream Products

220857-24-9Relevant academic research and scientific papers

Lewis acids accelerate reductive elimination of RCN from P2Pd(R)(CN)

Huang, Jinkun,Haar, Christopher M.,Nolan, Steven P.,Marcone, John E.,Moloy, Kenneth G.

, p. 297 - 299 (2008/10/08)

The rate of reductive elimination of the complexes dpppPd(CH2TMS)(CNER3) (E = B, Al) is accelerated up to 60-fold over dpppPd(CH2TMS)(CN). Based on kinetic considerations and the isoelectronic relationship of CN- and CO, a migration-type mechanism for reductive elimination is proposed. The rate acceleration correlates directly with Lewis acid strength, the latter determined by solution calorimetric analyses of the Lewis acid adduct forming reaction Pd-CN + ER3 → Pd-CN-ER3.

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