22094-20-8Relevant academic research and scientific papers
Synthesis of novel zwitterionic heterogemini surfactants derived from fatty acid and investigation of their behavior at the air-water interface
Yu, Erlei,Mamat, Xamxikamar,Zhang, Yagang,Eli, Wumanjiang
, p. 591 - 597 (2015/10/05)
Series of novel cationic-non-ionic heterogemini surfactants (Cn-1EC-s-Cm where n and m represents the hydrocarbon chain length of fatty acid and aliphatic amine, n=12, 14, 16, 18, m=12, 14, 16) were synthesized from fatty acid, epichlorohydrin and aldciphatic amine. The chemicals tructures of the surfactants were characterized by IR spectra, NMR, ESI-MS and elemental analysis. Their critical micelle concentrations (CMC) in the aqueous solutions were determined by surface-tension at 25°C. Relationship betweenγcmc and hydrophobic chain length was established which showed a large increase upon increasing of chain length with ester. The surface-tension measurements of Cn-1EC-s-Cm showed a low CMC, which greatly improve the efficiency in lowering the surface tension. Furthermore, adsorption and micellization behavior of Cn-1EC-s-Cm were investigated by measuring minimum average area per surfactant molecule and standard free energy.
Synthesis of novel zwitterionic heterogemini surfactants derived from fatty acid and investigation of their behavior at the air-water interface
Yu, Erlei,Mamat, Xamxikamar,Zhang, Yagang,Eli, Wumanjiang
, p. 591 - 597 (2016/10/05)
A series of novel cationic-non-ionic heterogemini surfactants (Cn-1EC-s-Cm where n and m represents the hydrocarbon chain length of fatty acid and aliphatic amine, n=12, 14, 16, 18, m=12, 14, 16) were synthesized from fatty acid, epichlorohydrin and aldciphatic amine. The chemicals tructures of the surfactants were characterized by IR spectra, NMR, ESI-MS and elemental analysis. Their critical micelle concentrations (CMC) in the aqueous solutions were determined by surface-tension at 25°C.Relationship betweenγcmc and hydrophobic chain length was established which showed a large increase upon increasing of chain length with ester. The surface-tension measurements of Cn-1EC-s-Cm showed a low CMC, which greatly improve the efficiency in lowering the surface tension. Furthermore, adsorption and micellization behavior of Cn-1EC-s-Cm were investigated by measuring minimum average area per surfactant molecule and standard free energy.
