221015-75-4

Upstream product

• 100-51-6 benzyl alcohol 
• 27393-97-1 (E)-3-(2-furanyl)-2-propen-1-ol 
• 221015-69-6 (3S,4S,5R,6S)-3,4,5-Tris-benzyloxy-6-vinyl-tetrahydro-pyran-2-one 
• 221015-71-0 (3R,4S,5R,6S)-3,4,5-Tris-benzyloxy-6-vinyl-tetrahydro-pyran-2-one 
• 221015-56-1 ((1S,2S,3S,4S,5S,7R)-2,3,4-Tris-benzyloxy-6,8-dioxa-bicyclo[3.2.1]oct-7-yl)-methanol 
• 221015-58-3 (1R,2S,3S,4S,5R,7S)-2,3,4-Tris-benzyloxy-7-iodomethyl-6,8-dioxa-bicyclo[3.2.1]octane 
• 221015-54-9 tert-Butyl-dimethyl-((1S,2S,3S,4S,5S,7R)-2,3,4-tris-benzyloxy-6,8-dioxa-bicyclo[3.2.1]oct-7-ylmethoxy)-silane 
• 53282-12-5 ethyl (E)-3-(2-furyl)prop-2-enoate 
• 221015-52-7 (1S,2S,3R,4S,5S,7R)-2-Benzyloxy-7-(tert-butyl-dimethyl-silanyloxymethyl)-6,8-dioxa-bicyclo[3.2.1]octane-3,4-diol 
• 221015-50-5 ((1R,2S,5S,7R)-2-Benzyloxy-6,8-dioxa-bicyclo[3.2.1]oct-3-en-7-ylmethoxy)-tert-butyl-dimethyl-silane 
• 221015-44-7 (1S,2R)-3-(tert-Butyl-dimethyl-silanyloxy)-1-furan-2-yl-propane-1,2-diol 
• 221015-49-2 (1R,2S,5S,7R)-7-(tert-Butyl-dimethyl-silanyloxymethyl)-6,8-dioxa-bicyclo[3.2.1]oct-3-en-2-ol 
• 221015-46-9 (1S,5S,7R)-7-(tert-Butyl-dimethyl-silanyloxymethyl)-6,8-dioxa-bicyclo[3.2.1]oct-3-en-2-one 
• 221015-42-5 tert-Butyl-((E)-3-furan-2-yl-allyloxy)-dimethyl-silane 

Downstream Products

• 221015-77-6 ((2S,3R,4S,5R)-3,4,5,6-Tetrakis-benzyloxy-tetrahydro-pyran-2-yl)-methanol 

Relevant academic research and scientific papers

Back to the sugars: A new enantio and diastereocontrolled route to hexoses from furfural

An integrated enantio and diastereocontrolled route to both enantiomers of the eight possible hexoses has been explored starting from furfural, by employing the Sharpless asymmetric dihydroxylation as a key step. At the present, a route to six of the eight possible hexoses has been established. The present synthesis may be taken as a reversion of the sugar-originated furfural to the sugars via a levoglucosenone, a pyrolysate of cellulose, type intermediate.