221015-89-0

Basic information

• Product Name: ((2S,3R,4R,5S)-3,4,5,6-Tetrakis-benzyloxy-tetrahydro-pyran-2-yl)-methanol
• Synonyms: ((2S,3R,4R,5S)-3,4,5,6-Tetrakis-benzyloxy-tetrahydro-pyran-2-yl)-methanol
• CAS NO: 221015-89-0
• Molecular Weight: 540.656
• Mol File: 221015-89-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: ((2S,3R,4R,5S)-3,4,5,6-Tetrakis-benzyloxy-tetrahydro-pyran-2-yl)-methanol(CAS DataBase Reference)
• NIST Chemistry Reference: ((2S,3R,4R,5S)-3,4,5,6-Tetrakis-benzyloxy-tetrahydro-pyran-2-yl)-methanol(221015-89-0)
• EPA Substance Registry System: ((2S,3R,4R,5S)-3,4,5,6-Tetrakis-benzyloxy-tetrahydro-pyran-2-yl)-methanol(221015-89-0)

Safety Data

• Hazardous Substances Data: 221015-89-0(Hazardous Substances Data)

Upstream product

• 53282-12-5 ethyl (E)-3-(2-furyl)prop-2-enoate 
• 221015-43-6 (E)-3-(2-Furyl)prop-2-enyl (2-naphthylmethyl) ether 
• 27393-97-1 (E)-3-(2-furanyl)-2-propen-1-ol 
• 221015-88-9 (3S,4R,5R,6S)-2,3,4,5-Tetrakis-benzyloxy-6-vinyl-tetrahydro-pyran 
• 221015-86-7 (1R,2S,3R,4S,5R,7S)-2,3,4-Tris-benzyloxy-7-iodomethyl-6,8-dioxa-bicyclo[3.2.1]octane 
• 221015-85-6 ((1S,2S,3R,4S,5S,7R)-2,3,4-Tris-benzyloxy-6,8-dioxa-bicyclo[3.2.1]oct-7-yl)-methanol 
• 221015-84-5 (1S,2S,3R,4S,5S,7R)-2,3,4-Tris-benzyloxy-7-(naphthalen-2-ylmethoxymethyl)-6,8-dioxa-bicyclo[3.2.1]octane 
• 221015-82-3 (+)-(1S,2S,3S,4S,5S,7R)-2-Benzoyloxy-3,4-epoxy-7-(2-naphthylmethyloxymethyl)-6,8-dioxabicyclo[3.2.1]octane 
• 221015-78-7 (+)-(1S,3R,4S,5S,7R)-3,4-Epoxy-7-(2-naphthylmethyloxymethyl)-6,8-dioxabicyclo[3.2.1]octan-2-one 
• 1027995-87-4 (S)-6-Hydroxy-2-[(R)-1-hydroxy-2-(naphthalen-2-ylmethoxy)-ethyl]-6H-pyran-3-one 
• 221015-83-4 (+)-(1R,2S,3R,4S,5S,7R)-2,3,4-Trihydroxy-7-(2-naphthylmethyloxymethyl)-6,8-dioxabicyclo[3.2.1]octane 
• 221015-47-0 (+)-(1S,5S,7R)-7-(2-Naphthylmethyloxymethyl)-6,8-dioxabicyclo[3.2.1]oct-3-en-2-one 
• 221015-80-1 (-)-(1R,2S,3S,4S,5S,7R)-3,4-Epoxy-2-hydroxy-7-(2-naphthylmethyloxymethyl)-6,8-dioxabicyclo[3.2.1]octane 
• 221015-45-8 (+)-(1S,2R)-1-(2-Furyl)-3-(2-naphthylmethyloxy)propane-1,2-diol 

Downstream Products

• 15572-79-9 aldehydo-L-Galactose 

Relevant articles and documents

Back to the sugars: A new enantio and diastereocontrolled route to hexoses from furfural

An integrated enantio and diastereocontrolled route to both enantiomers of the eight possible hexoses has been explored starting from furfural, by employing the Sharpless asymmetric dihydroxylation as a key step. At the present, a route to six of the eight possible hexoses has been established. The present synthesis may be taken as a reversion of the sugar-originated furfural to the sugars via a levoglucosenone, a pyrolysate of cellulose, type intermediate.