221021-70-1

Basic information

• Product Name: 1,1'-bis(diphenylphosphino)ferrocenepalladium(η(2)-methylacrylate)
• Synonyms: 1,1'-bis(diphenylphosphino)ferrocenepalladium(η(2)-methylacrylate)
• CAS NO: 221021-70-1
• Molecular Weight: 746.901
• Mol File: 221021-70-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1,1'-bis(diphenylphosphino)ferrocenepalladium(η(2)-methylacrylate)(CAS DataBase Reference)
• NIST Chemistry Reference: 1,1'-bis(diphenylphosphino)ferrocenepalladium(η(2)-methylacrylate)(221021-70-1)
• EPA Substance Registry System: 1,1'-bis(diphenylphosphino)ferrocenepalladium(η(2)-methylacrylate)(221021-70-1)

Safety Data

• Hazardous Substances Data: 221021-70-1(Hazardous Substances Data)

Upstream product

• 72287-26-4 (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride 
• 292638-85-8 acrylic acid methyl ester 

Downstream Products

• 253872-49-0 (NO₂C₆H₄)Pd(OCOCH₃)(((C₆H₅)2PC₅H₄)2Fe) 
• 253872-47-8 (NO₂C₆H₄)PdCl(((C₆H₅)2PC₅H₄)2Fe) 
• 253872-53-6 (C₆H₅)PdCl(((C₆H₅)2PC₅H₄)2Fe) 
• 253872-50-3 ((CF₃)2C₆H₃)PdCl(((C₆H₅)2PC₅H₄)2Fe) 

Relevant articles and documents

Factors affecting the oxidative addition of aryl electrophiles to 1,1′-bis(diphenylphosphino)ferrocenepalladium(η2-methyl acrylate), an isolable Pd[0] alkene complex

The title complex 3 has been synthesized and characterized by X-ray crystallography. It undergoes oxidative addition with aryl triflates and iodides by a nondissociative mechanism in THF. The Heck addition product methyl cinnamate was detected at traces from the reaction with phenyl triflate, and from iodobenzene the direct oxidative addition product was characterized. The addition of halides or acetate salts to the system led to modest effects on the rate of oxidative addition of aryl triflates, but resulted in neutral arylpalladium(II) complexes. Addition of lithium or europium salts enhanced the reaction rate, the effect being most pronounced with Eu(OTf)3, possibly through promotion of a competing dissociative pathway.