221041-18-5

Basic information

• Product Name: 1-phenylchlorothiophosphino-1,2-dicarba-closo-dodecaborane⁽¹²⁾
• Synonyms: 1-phenylchlorothiophosphino-1,2-dicarba-closo-dodecaborane⁽¹²⁾
• CAS NO: 221041-18-5
• Molecular Weight: 318.818
• Mol File: 221041-18-5.mol

Chemical Properties

• CAS DataBase Reference: 1-phenylchlorothiophosphino-1,2-dicarba-closo-dodecaborane⁽¹²⁾(CAS DataBase Reference)
• NIST Chemistry Reference: 1-phenylchlorothiophosphino-1,2-dicarba-closo-dodecaborane⁽¹²⁾(221041-18-5)
• EPA Substance Registry System: 1-phenylchlorothiophosphino-1,2-dicarba-closo-dodecaborane⁽¹²⁾(221041-18-5)

Safety Data

• Hazardous Substances Data: 221041-18-5(Hazardous Substances Data)

Upstream product

• 644-97-3 Dichlorophenylphosphine 
• 221041-14-1 1-phenylchlorophosphino-1,2-dicarba-closo-dodecaborane⁽¹²⁾ 

Relevant articles and documents

The reaction of phenylchlorophosphino-substituted 1,2-dicarba-closo-dodecaboranes(12) with elemental sulfur and molecular structures of rac-1,2-bis(phenylchlorophosphino)-1,2-dicarba-closo-dodecaborane(12) and 1-phenylchlorothiophosphino-2-phenyl-1,2-dicarba-closo-dodecaborane(12)

rac-1,2-Bis(phenylchlorophosphino)-1,2-dicarba-closo-dodecaborane(12) (1) reacts with four equivalents of sulfur at 185-190°C in undecane to give the cyclic anhydride of 1,2-bis(phenylthiophosphoryl)-1,2-dicarba-closo-dodecaboranyl(12)- dithiodiphosphinic acid (2). Under comparable conditions, 1-phenyl-chlorophosphino-1,2-dicarba-closo-dodecaborane(12) (4) and 1-phenyl-chlorophosphino-2-phenyl-1,2-dicarba-closo-dodecaborane(12) (5) react with sulfur to give 1-phenylchlorothiophosphino-1,2-dicarba-closo-dodecaborane(12) (6) and 1-phenylchlorothiophosphino-2-phenyl-1,2-dicarba-closo-dodecaborane(12) (7). Compounds 4-7 were characterized by 1H, 31P, 13C and 11B NMR spectroscopy and elemental analysis, and X-ray structure determinations were carried out on 1 and 7.