22110-53-8

Usage

Uses

Used in Organic Synthesis:
1-Adamantaneisocyanide is used as a building block in organic synthesis for its ability to facilitate the preparation of a wide range of compounds. Its unique structure and reactivity contribute to the creation of diverse organic molecules.
Used in Pharmaceutical Industry:
1-Adamantaneisocyanide is used as a precursor in the synthesis of pharmaceuticals due to its capacity to form complex molecular structures that can have therapeutic effects. Its versatility in organic chemistry allows for the development of new drugs with potential medicinal applications.
Used in Agrochemical Industry:
1-Adamantaneisocyanide is utilized in the agrochemical field as a starting material for the synthesis of various agrochemicals, including pesticides and herbicides. Its properties enable the creation of compounds that can effectively control pests and weeds in agricultural settings.

InChI:InChI=1/C11H15N/c1-12-11-5-8-2-9(6-11)4-10(3-8)7-11/h8-10H,2-7H2

Upstream product

• 431946-35-9 1-(1-adamantyl)-3-triphenylmethylaziridin-2-one 
• 85433-68-7 3-(1-Adamantyl)-3,5-dihydro-5,5-dimethyl-4H-1,2,3-triazol-4-on 

Downstream Products

• 722547-16-2 Mo(NCH(CH₃)2C₆H₃(CH₃)2)3CNC₁₀H₁₅ 
• 722547-17-3 (1-adamantylisocyanide)2Mo(N[i-Pr](3,5-C₆H₃Me₂)3 

Relevant academic research and scientific papers

Skeletal rearrangement of cyano-substituted iminoisobenzofurans into alkyl 2-cyanobenzoates catalyzed by B(C6F5)3

An efficient method for the direct conversion of cyano-substituted iminoisobenzofurans into their corresponding alkyl 2-cyanobenzoates has been developed. This transformation proceeds via cleavage of C-C, C-O, and C-N bonds in starting iminoisobenzofurans. DFT study revealed that intermediate α-iminonitriles are produced in situ via C-C bond formation between 2-iminium benzoates and a cyanide ion. Generation of isocyanide as the byproduct in a more thermodynamic manner in DFT calculations also supports the experimental results.

About four new trityl-substituted α-lactams

This investigation comprises the synthesis, a description of the physical and spectroscopic properties, determination of the limits of thermal stability, and reactions with protic and aprotic nucleophiles of four new trityl-substituted α-lactams. With the exception of 3,3-dimethyl-1-tritylaziridin-2-one (4a), which is unstable at room temperature, all new compounds have been fully characterized.

COMPETING PATHWAYS IN THE PHOTODENITROGENATION OF A 3,5-DIHYDRO-4H-1,2,3-TRIAZOL-4-ONE. A NOVEL ROUTE TO AZIRIDINONES

The photodenitrogenation of the 3,5-dihydro-4H-1,2,3-triazol-4-one 6, obtained from 1-azidoadamantane (5) and the lithium enolate of methyl isobutyrate, produced acetone, the isocyanide 10 and the aziridinone 7, which was solvolysed to the α-methoxy amide 8 during photolysis in 4>methanol.