22112-75-0Relevant academic research and scientific papers
The Mixed-Aldehyde Synthesis of Difunctional Tetraarylporphyrins
Little, Robert G.
, p. 129 - 133 (2007/10/02)
The synthesis is reported of nine umsymmetrical, meso-substituted porphyrins.Among the compounds prepared are the following 5-(R)-10,15,20-tri-p-tolylporphyrins; R = 2,6-dinitrophenyl, 4-hydroxy-3-ethoxyphenyl,4-hydroxy-3-methoxy-5-nitrophenyl, 5-hydroxy-2-nitrophenyl and 4-hydroxy-3-nitrophenyl.Other porphyrins reported include 5-(2-(1-butoxy)phenyl)-15-(2-nitrophenyl)-10,15-di-p-tolylporphyrin and the two 5-(R)-10,15,20-tripropylporphyrins in which R = 2-nitrophenyl and 2-hydroxyphenyl.The disubstituted porphyrins offer a rational route to the synthesis of difunctional "tailed-porphyrins".
