22115-06-6Relevant articles and documents
Oxidative cleavage of C=C bonds with singlet molecular oxygen generated from monoacetylated bishydroperoxides
Azarifar, Davood,Najminejad, Zohreh
, p. 1377 - 1382 (2013/07/26)
The oxidative cleavage of C=C bonds adjacent to aryl and alkyl moieties was efficiently achieved with monoacetylated bishydroperoxides. The main active oxidant used in this reaction was singlet molecular oxygen, which was generated in situ from the base-mediated fragmentation of monoacetylated bishydroper oxides. All the reactions proceeded smoothly at room temperature to furnish the respective carbonyl compounds in good yields within short reaction times. Georg Thieme Verlag Stuttgart · New York.