22116-67-2

Basic information

• Product Name: (4-methylsulfanylbenzylidene)phenylamine
• Synonyms: (4-methylsulfanylbenzylidene)phenylamine
• CAS NO: 22116-67-2
• Molecular Weight: 227.33
• Mol File: 22116-67-2.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: (4-methylsulfanylbenzylidene)phenylamine(CAS DataBase Reference)
• NIST Chemistry Reference: (4-methylsulfanylbenzylidene)phenylamine(22116-67-2)
• EPA Substance Registry System: (4-methylsulfanylbenzylidene)phenylamine(22116-67-2)

Safety Data

• Hazardous Substances Data: 22116-67-2(Hazardous Substances Data)

Upstream product

• 62-53-3 aniline 
• 3446-89-7 4-(Methylthio)benzaldehyde 
• 98-95-3 nitrobenzene 
• 723753-86-4 N-((4-methylthio)benzyl)benzenamine 
• 3446-90-0 4-(methylthio)benzyl alcohol 

Downstream Products

• 1448450-17-6 3-(4-(methylthio)phenyl)-2-phenylisoquinolin-1(2H)-one 
• 1586046-87-8 N-(4-(methylsulfinyl)benzylidene)aniline 
• 1376298-97-3 2-(4-methylsulfonylphenyl)-3-phenyl-1,3-benzdiazinan-4-one 
• 1239645-71-6 N‐(4‐(methylsulfonyl)benzylidene)aniline 
• 434294-70-9 2-(4-(methylthio)phenyl)-3-phenyl-1,3-benzdiazinan-4-one 
• 723753-86-4 N-((4-methylthio)benzyl)benzenamine 

Relevant articles and documents

Photoredox-Catalyzed Synthesis of α-Amino Acid Amides by Imine Carbamoylation

An operationally simple protocol for the photocatalytic carbamoylation of imines is reported. Easily available, bench-stable 4-amido Hantzsch ester derivatives serve as precursors to carbamoyl radicals that undergo rapid addition to N-aryl imines. The reaction proceeds under blue light irradiation in the presence of the photocatalyst 3DPAFIPN and Br?nsted/Lewis acid additives. Mechanistic studies indicated a photoredox mechanism that involves carbamoyl radicals.

Direct synthesis of imines by 9-azabicyclo-[3,3,1]nonan-N-oxyl/KOH-catalyzed aerobic oxidative coupling of alcohols and amines

A simple and efficient method for preparation of imines by the oxidative coupling of benzyl alcohols with aromatic amines or aliphatic amines was developed. The reaction was catalyzed by 9-azabicyclo[3.3.1]nonan-N-oxyl (ABNO)/KOH with air as the economic and green oxidant. Under the optimal reaction conditions, a variety of imines were obtained in 80%-96% isolated yields.

General and selective reductive amination of carbonyl compounds using a core-shell structured Co3O4/NGr@C catalyst

The application of heterogenized non-noble metal-based catalysts in selective catalytic hydrogenation processes is still challenging. In this respect, the preparation of a well-defined cobalt-based catalyst was investigated by immobilization of the corresponding cobalt(ii)-phenanthroline-chelate on Vulcan XC72R carbon powder. The formed core-shell structured cobalt/cobalt oxide nanocomposites are encapsulated by nitrogen-enriched graphene layers. This promising cheap heterogeneous catalyst allows for an efficient domino reductive amination of carbonyl compounds with nitroarenes. This journal is