221216-38-2Relevant academic research and scientific papers
A stereoselective total synthesis of xyolide, a natural bioactive nonenolide
Maram, Lingaiah,Das, Biswanath
, p. 674 - 682 (2015/06/02)
A stereoselective total synthesis of xyolide, a naturally occurring bioactive nonenolide, has been accomplished. The acid fragment of the molecule has been prepared from D-mannitol and the alcohol fragment from (2Z)-but-2-ene-1,4-diol. The synthesis invol
Formal synthesis of herbarumin-I
Reddy, N. Salva,Lingaiah,Das, Biswanath
, p. 389 - 394 (2019/01/21)
The formal synthesis of herbarumin-I has been accomplished by srereoselective preparation of its alcohol fragment and its diastereoisomer starting from cis but-2-en- 1,4-diol. Both the diastereoisomeric alcohols were esterified with 5-hexenoic acid by app
A NEW SYNTHETIC METHOD FOR γ-BUTYROLACTOLS BY THE PALLADIUM-CATALYZED REGIOSELECTIVE OXIDATION OF 1-ALKEN-4-OLS
Nokami, Junzo,Ogawa, Hideki,Miyamoto, Shinya,Mandai, Tadakatsu,Wakabayahi, Shoji,Tsuji, Jiro
, p. 5181 - 5184 (2007/10/02)
3-substituted 1-alken-4-ols were oxidized with PdCl2-benzoquinone regioselectively at the terminal carbon to afford cyclic hemiacetals (γ-butyroacetols), which were converted to γ-butiroacetones by the Jones oxidation.This reactions was applied to the synthesis of optically active deoxyribose and γ-butenolides.
