221247-27-4Relevant academic research and scientific papers
Two diphenylformamidinate compounds of the quadruply-bonded Re26+ core
Cotton, F. Albert,Daniels, Lee M.,Haefner, Steven C.
, p. 149 - 151 (1999)
The compounds Re2(DPhF)3Cl3 and Re2(DPhF)2Cl4 have been prepared and structurally characterized (DPhF = anion of N,N-diphenylformamidine). The former has three bridging DPhF ligands, two equatorial Cl ligands and one axial Cl ligand. The Re-Re distances in two different crystallographic forms are 2.2318(8) A and 2.2288(9) A. The second compound has two trans DPhF ligands and the Re2Cl4 unit is planar with Re-Re = 2.177(1) A, Re-Cl(av) = 2.319(5) A, Re-N(av) = 2.06(1) A and Cl-Re-Cl(av) = 106.0(1)°.
