221247-31-0Relevant articles and documents
Platinum(II) and palladium(II) saccharinate complexes
Henderson, William,Nicholson, Brian K.,McCaffrey, Louise J.
, p. 145 - 148 (1999)
A number of platinum(II) and palladium(II) complexes containing the saccharinate ligand (sac-), of the type [MCl(sac)L2] (M = Pt, L = PPh3, L2 = Ph2PCH2CH2PPh2, dppe; M = Pd, L = PPh3) have been synthesised by reaction of [MCl2L2] with sacNa in methanol. A single crystal X-ray diffraction study carried out on cis-[PtCl(sac)(PPh3)2]·4CHCl3 shows the N-bonded saccharinate and platinum coordination planes to be nearly orthogonal. The results of an electrospray mass spectrometric study of the dppe complex are also reported.