221247-56-9Relevant academic research and scientific papers
Unusual coordination mode of a 2-pyridyl ketone oxime ligand in bis(4-butylphenyl 2-pyridyl ketone oximate)palladium(II)
Carcelli, Mauro,Cozzini, Pietro,Marroni, Romina,Pelagatti, Paolo,Pelizzi, Corrado,Sgarabotto, Paolo
, p. 138 - 141 (1999)
In the complex PdL2 (HL = 4-butylphenyl 2-pyridyl ketone oxime), characterised by spectroscopic techniques and X-ray diffraction analysis, the deprotonated ligand displays a N,O coordination, with the pyridyl nitrogen and the oxime oxygen, which is without precedence in this class of compounds; 1H NMR spectra, together with structural data on PdL2, make it possible to distinguish between the N,O and N,N coordination mode in analogous compounds.
