2216-36-6Relevant articles and documents
Cobalt(II)-Porphyrin Catalyzed Selective Functionalization of Alkanes with sulfurylchloride: A Remarkable Substituent Effect
Khanna, Vibha,Tamilselvan, Pitchiah,Kalra, Swinder Jeet Singh,Iqbal, Javed
, p. 5935 - 5938 (2007/10/02)
Cobalt(II)-porphyrin complex 1 and 2 catalyses the chlorination and sulfochlorination respectively of n-alkanes and cycloalkanes with sulfuryl chloride in benzene.The p-substituent of the benzene ring in the porphyrin complex 1 and 2 shows a remarkable chemoselectivity in these reactions.