22161-54-2Relevant academic research and scientific papers
Chelation-assisted cross-coupling of anilines through in situ activation as diazonium salts with boronic acids under ligand-, base-, and salt-free conditions
Joncour, Roxan,Susperregui, Nicolas,Pinaud, Noel,Miqueu, Karinne,Fouquet, Eric,Sotiropoulos, Jean-Marc,Felpin, Francois-Xavier
, p. 9291 - 9296 (2013)
We describe the coupling of anilines with aryl boronic acids, under ligand-, base-, and salt-free conditions at room temperature. This new reaction proceeds through the formation of an aryl palladium alkoxo complex, which allows the transmetalation step w
