221657-61-0

Basic information

• Product Name: 1,5-Anhydro-4-O-<3,4-bis-O-(tert-butyldiphenylsilyl)-6-deoxy-2-phenylseleno-β-L-gluco-pyranosyl>-3-O-(tert-butyldimethylsilyl)-2,6-dideoxy-L-arabino-hex-1-enitol
• Synonyms: 1,5-Anhydro-4-O-<3,4-bis-O-(tert-butyldiphenylsilyl)-6-deoxy-2-phenylseleno-β-L-gluco-pyranosyl>-3-O-(tert-butyldimethylsilyl)-2,6-dideoxy-L-arabino-hex-1-enitol
• CAS NO: 221657-61-0
• Molecular Weight: 1006.42
• Mol File: 221657-61-0.mol

Chemical Properties

• CAS DataBase Reference: 1,5-Anhydro-4-O-<3,4-bis-O-(tert-butyldiphenylsilyl)-6-deoxy-2-phenylseleno-β-L-gluco-pyranosyl>-3-O-(tert-butyldimethylsilyl)-2,6-dideoxy-L-arabino-hex-1-enitol(CAS DataBase Reference)
• NIST Chemistry Reference: 1,5-Anhydro-4-O-<3,4-bis-O-(tert-butyldiphenylsilyl)-6-deoxy-2-phenylseleno-β-L-gluco-pyranosyl>-3-O-(tert-butyldimethylsilyl)-2,6-dideoxy-L-arabino-hex-1-enitol(221657-61-0)
• EPA Substance Registry System: 1,5-Anhydro-4-O-<3,4-bis-O-(tert-butyldiphenylsilyl)-6-deoxy-2-phenylseleno-β-L-gluco-pyranosyl>-3-O-(tert-butyldimethylsilyl)-2,6-dideoxy-L-arabino-hex-1-enitol(221657-61-0)

Safety Data

• Hazardous Substances Data: 221657-61-0(Hazardous Substances Data)

Upstream product

• 5707-04-0 Phenylselenyl chloride 
• 101856-96-6 (2S,3S,4S)-4-(tert-butyldimethylsilyloxy)-3,4-dihydro-3-hydroxy-2-methyl-2H-pyran 
• 221657-96-1 Acetyl 3,4-bis-O-(tert-butyldiphenylsilyl)-6-deoxy-2-phenylseleno-β-L-gluco-pyranose 

Downstream Products

• 221657-83-6 1,5-Anhydro-4-O-<3,4-bis-O-(tert-butyldiphenylsilyl)-6-deoxy-2-phenylseleno-β-L-gluco-pyranosyl>-2,6-dideoxy-L-erythro-hex-1-en-3-ulose 

Relevant articles and documents

Simple oxidation of 3-O-silylated glycals: Application in deblocking 3-0-protected glycals

A high yielding allylic oxidation of 3-O-siIylated glycals 5-10 with the reagent system PhI(OAc)2-TMSN3 is presented. The iodine(m) species generated under these conditions is a lot more effective for generating carbohydrate-derived 3-trialkylsiloxy-2,3-d