22166-04-7

Upstream product

• 1193-55-1 2-methylcyclohexane-1,3-dione 
• 107-13-1 acrylonitrile 

Downstream Products

• 109214-42-8 3-((1R,2R)-2-Hydroxy-1-methyl-6-oxo-cyclohexyl)-propionitrile 
• 109214-43-9 (2R,3S)-2-(cyanoethyl)-3-hydroxy-2-methylcyclohexanone 
• 109214-44-0 3-((1S,2R)-2-Hydroxy-1-methyl-6-oxo-cyclohexyl)-propionitrile 
• 109214-41-7 (2S,3S)-2-(cyanoethyl)-3-hydroxy-2-methylcyclohexanone 

Relevant academic research and scientific papers

Intramolecular [3+2]-hetero-annulation of allylsilanes with 1,3-cyclohexanediones and its application in the synthesis of hexacyclic hopane triterpenes

In this letter we describe the intramolecular [3+2]-hetero-annulation of allylsilanes with 1,3-cyclohexanediones followed by sila-Wagner-Meerwein shift. The new synthesis of the cyclization precursors offers the advantage to vary the silyl terminator at t

Asymmetric Microbial Reduction of Prochiral 2,2-Disubstituted Cycloalkanediones

Asymmetric microbial reduction of a series of 2,2-disubstituted 1,3-cycloalkanediones with bakers' yeast was examined as an example of an enzyme-catalyzed distinction of a substrate containing two trigonal carbonyl centers with stereoheterotropic faces an