221676-20-6Relevant articles and documents
A tripartite asymmetric allylboration - Silicon tethered alkene ring closing metathesis - In situ ring opening protocol for the regiospecific generation of functionalized (E)-disubstituted homoallylic alcohols
Ahmed, Mahmood,Barrett, Anthony G. M.,Beall, Jennifer C.,Braddock, D. Christopher,Flack, Kevin,Gibson, Vernon C.,Procopiou, Panayiotis A.,Salter, Matthew M.
, p. 3219 - 3232 (2007/10/03)
Molybdenum carbene 6 catalyzed ring closing metathesis of (alkenyl)silyl ethers of homochiral allylic alcohols to afford 1,2-oxasilines which were elaborated in situ to give (E)-4-alkyl-1,2-disubstituted 3-buten-1-ol and (Z)-4-alkyl-4-silyl-1,2-disubstituted 3-buten-1-ol derivatives as single geometric isomers.
