221676-50-2Relevant academic research and scientific papers
Novel, strained 10b,10c-dihydropyrenes bearing bulky TMSCH2 groups at the internal positions
Sawada, Tsuyoshi,Wakabayashi, Masaki,Takeo, Hiromi,Miyazawa, Akira,Tashiro, Masashi,Thiemann, Thies,Mataka, Shuntaro
, p. 403 - 407 (2007/10/03)
Two novel, strained trans-10b,10c-dihydropyrenes, 9a-b, with internal, bulky trimethylsilylmethyl substituent(s) were synthesized. Their 14π-electron annulene systems were found to be distorted, as shown by X-ray crystallographic analyses and 1H-NMR and UV spectroscopy.
