221874-54-0Relevant academic research and scientific papers
Study on fungitoxic 3-amino-2-piperidinone-containing lipids: Revised structure of cepaciamide A and structural determination of its closely related lipid, cepaciamide B
Toshima, Hiroaki,Maru, Kazuko,Jiao, Ying,Yoshihara, Teruhiko,Ichihara, Akitami
, p. 935 - 938 (1999)
The structure of cepaciamide A was revised to be (3R,3'S,2'S,11'S,12'R)- 3-[3'-(2'hydroxy-11', 12'-methylencoetadecanoyloxy)hexadecamido]-2- piperidinone with respect to the absolute configuration of the C3- and C2- positions and the position of the cyclopropane ring by using synthetic methods. The structure of cepaciamide B was also determined to be (3R,3'S,2'S, 11'Z)'3'[3'(2'-hydroxy-11-octadecenoyloxy)hexadecamido]-2- piperidinone.
