22191-69-1Relevant academic research and scientific papers
1,5-Dipolar electrocyclizations in reactions of α-thioxo ketones and α-thioxo thioamides with diazo compounds
Egli, Daniel H.,Linden, Anthony,Heimgartner, Heinz
, p. 1910 - 1926 (2007/10/03)
Several reactions of α-thioxo ketones and α-thioxo thioamides with diazo compounds were investigated. Most of them proceeded via a reactive thiocarbonyl ylide, which underwent a [2+3] cycloaddition with the α-thioxo ketone to give the 'Schoenberg products
