222042-08-2Relevant academic research and scientific papers
An aromatic-antiaromatic switch in P-heteroles. A small change in delocalisation makes a big reactivity difference
Nyulaszi, Laszlo,Holloczki, Oldamur,Lescop, Christophe,Hissler, Muriel,Reau, Regis
, p. 996 - 998 (2006)
The low aromaticity of phosphole can be switched to low antiaromaticity by oxidizing the phosphorus atom. This subtle change in the mode of delocalisation alters substantially the chemical behaviour of these heteroles. The Royal Society of Chemistry 2006.
Phosphole-containing π-conjugated systems: From model molecules to polymer films on electrodes
Hay, Caroline,Hissler, Muriel,Fischmeister, Cedric,Rault-Berthelot, Joelle,Toupet, Loic,Nyulaszi, Laszlo,Reau, Regis
, p. 4222 - 4236 (2007/10/03)
Two series of 2,5-dipyridyland 2,5-dithienylphosphole derivatives containing σ3- or σ4-P atoms were prepared, and their optical (UV/Vis absorption, fluorescence spectra) and electrochemical properties were systematically evaluated. These physic
2,5-Di(2-pyridyl)phospholes: Model compounds for the engineering of π-conjugated donor-acceptor co-oligomers with a chemically tunable HOMO-LUMO gap
Hay, Caroline,Le Vilain, Delphine,Deborde, Valerie,Toupet, Loic,Reau, Regis
, p. 345 - 346 (2007/10/03)
2,5-Di(2-pyridyl)phospholes possess an extended π-conjugated system with a charge transfer structure; high yielding chemical modifications involving the phosphorus atom allow fine tuning of the HOMO-LUMO gap.
