222300-44-9

Upstream product

• 1445-45-0 Trimethyl orthoacetate 
• 133398-24-0 (E)-(3S)-1-(dimethylphenylsilyl)-1-buten-3-ol 
• 766-77-8 Dimethylphenylsilane 

Downstream Products

• 198758-05-3 (R)-4-(dimethyl(phenyl)silyl)dihydrofuran-2(3H)-one 
• 147060-58-0 (E)-(2R,5S,6R)-Methyl 2-acetoxy-6-(benzyloxy)-6-(2,3-dimethoxyphenyl)-5-methylhex-3-enoate 
• 146962-08-5 (2S,3R)-(E)-Methyl 2-acetoxy-3-(dimethylphenylsilyl)-hex-4-enoate 
• 146962-15-4 (E)-(2R,5S,6R)-Methyl 2-acetoxy-6-(2,5-dimethoxy-3-nitrophenyl)-6-methoxy-5-methylhex-3-enoate 
• 222300-33-6 (E)-3-(Dimethyl-phenyl-silanyl)-hex-4-en-1-ol 
• 146962-07-4 (2S,3R)-(E)-Methyl 3-(dimethylphenylsilyl)-2-hydroxy-hex-4-enoate 

Relevant academic research and scientific papers

Sequential Diastereoselective Addition and Palladium(II)-Catalyzed Allylic Acetate Transposition of syn- and anti-α-Acetoxy-β-silyl-(E)-hex-4-enoates with Achiral Acetals. Asymmetric Synthesis of Differentiated Syn and Anti 1,3-Diol Synthons

syn- and anti-Methyl α-acetoxy-β-(dimethylphenylsilyl)-(E)-hex-4-enoates, (2R,3R)-8a and (2S,3R)-8b, undergo highly diastereo- and enantioselective addition reactions with aldehydes and acetals 11 catalyzed by the action of trimethylsilyl trifluoromethane