222416-53-7Relevant academic research and scientific papers
Intramolecular Tishchenko reactions of protected hexos-5-uloses: A novel and efficient synthesis of L-idose and L-altrose
Adinolfi,Barone,De Lorenzo,Iadonisi
, p. 336 - 338 (1999)
Protected t-butyl esters of aldonic acids with the rare L-ido and L- altro configuration can be effectively obtained by a diastereoselective Tishchenko reaction of hexos-5-uloses induced by t-BuOSmI2. These compounds can be easily converted int
A Novel and Practical Synthesis of L-Hexoses from D-Glycono-1,5-lactones
Takahashi, Hideyo,Hitomi, Yuko,Iwai, Yoshinori,Ikegami, Shiro
, p. 2995 - 3000 (2007/10/03)
A novel and efficient conversion of D-glycono-1,5-lactones into the corresponding L-sugars is described. The important intermediate, δ-hydroxyalkoxamates, was provided by a practical alkoxyamination of D-glycono-1,5-lactones mediated by Me3Al.
