222636-76-2Relevant academic research and scientific papers
Synthesis of a configurationally stable three-legged piano-stool complex
Therrien, Bruno,K?nig, Adrian,Ward, Thomas R.
, p. 1565 - 1568 (1999)
Anchoring a phosphine and an enantiopure camphorpyrazole tether to an arene (PArN*) yields, after η6:η1:η1 coordination to ruthenium, [{η6:η1:η1-(PArN*)}-RuL] 2+ as a 1:1 mixture of diastereomers. These were separated and characterized by X-ray crystallography. The structure of the R,RP,SRu diastereomer is depicted.
