2227-27-2

Upstream product

• 931-51-1 cyclohexylmagnesiumchloride 

Downstream Products

• 107352-14-7 7,7,8,8-Tetracylohexyl-2,3:5,6-dibenzo-7,8-disilabicyclo<2.2.2>octa-2,5-dien 
• 107352-11-4 1,1,2,2-Tetracyclohexyl-1,2-dichlordisilan 
• 2227-34-1 Amino-dicyclohexyl-silan 
• 68750-07-2 1,1,2,2-tetracyclohexyldisilane 
• 18758-61-7 1,3-dihydro-1,1,3,3-tetracyclohexyldisiloxane 
• 15493-30-8 dicyclohexylsilane 
• 1629-47-6 tricyclohexylsilane 

Relevant academic research and scientific papers

Facile and Convergent Synthesis of Highly Fused Oligosiloles by Rhodium-Catalyzed Stitching Reaction

A facile and convergent synthesis of highly fused oligosiloles was achieved by utilizing the rhodium-catalyzed stitching reaction, an efficient synthetic method for ladder-type π-conjugated compounds recently developed in our group. Up to 11 rings could b

Cross-coupling reactions through the intramolecular activation of Alkyl(triorgano)silanes

(Figure Presented) Cross-Si-ing the Jordan: Cross-coupling reactions of 2-(2-hydroxyprop-2-yl)phenylsubstituted alkylsilanes with a variety of aryl halides proceed in the presence of palladium and copper catalysts. The use of K3PO4 base allows for highly chemoselective alkyl coupling with both primary and secondary alkyl groups (Alk).

Process for preparing alkylhydrogenchlorosilanes

Alkylhydrogenchlorosilanes of formula I: wherein R are identical or different alkyl radicals, x is 1 or 2 and y is 1 or 2 and the sum of x and y is equal to 3, are prepared by comproportionating alkylchlorosilanes of formula II: wherein R denotes identical or different alkyl radicals, a is 1 or 2 and n is 2 or 3 and the sum of a and n is equal to 4 with hydrogenchlorosilanes of formula III: wherein R denotes identical or different alkyl radicals, b is 0, 1, 2 or 3 and c is 1, 2, 3 or 4 and the sum of b and c is equal to or smaller than 4, in the presence of a catalyst saturated with a hydrogen halide.