2229-06-3Relevant academic research and scientific papers
Heats of Formation of Radicals and Molecules by a Photoacoustic Technique
Burkey, T. J.,Majewski, M.,Griller, D.
, p. 2218 - 2221 (2007/10/02)
A photoacoustic technique was used to measure heats of free radical reactions.To illustrate the method, bond dissociation energies were measured for the Sn-H bond in n-Bu3SnH, for the C3-H bond in 1,4-cyclohexadiene, and for the C2-H bond in diethyl ether.Heats of formation of t-BuOPPh3 and t-BuOP(Bu-n)2 were determined, and the method was also used to measure quantum yields for the photolysis of di-tert-butyl peroxide and diphenyl disulfide.
