223386-93-4

Basic information

• Product Name: C₂₇H₄₀S₄Si₂
• Synonyms: C₂₇H₄₀S₄Si₂
• CAS NO: 223386-93-4
• Molecular Weight: 549.05
• Mol File: 223386-93-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₂₇H₄₀S₄Si₂(CAS DataBase Reference)
• NIST Chemistry Reference: C₂₇H₄₀S₄Si₂(223386-93-4)
• EPA Substance Registry System: C₂₇H₄₀S₄Si₂(223386-93-4)

Safety Data

• Hazardous Substances Data: 223386-93-4(Hazardous Substances Data)

Upstream product

• 13411-42-2 2-(trimethylsilyl)-1,3-dithiane 
• 6940-76-7 1-iodo-3-chloro-propane 
• 135746-47-3 2-methyldiphenylsilyl-1,3-dithiane 

Downstream Products

• 223386-88-7 1-(methyl-diphenyl-silanyl)-5-trimethylsilanyl-pentane-1,5-dione 

Relevant articles and documents

Synthesis of symmetrical and unsymmetrical 2,5-bis(trialkylsilyl)furans and 2,6-bis(trialkylsilyl)-4H-pyrans from 1,4- and 1,5-bis(acylsilanes)

2,5-Bis(trialkylsilyl)furans and 2,6-bis(trialkylsilyl)-4Hpyrans have been synthesized by cyclodehydration of 1,4- and 1,5-bis(acylsilanes) under p-toluenesulfonic acid catalysis. The 1,4-bis(acylsilanes) have been prepared from 1,2-bis(1,3-dithian-2yl)ethane according to the reaction sequence metallation-silylationdethioketalization. The 1,5-bis(acylsilanes) have been prepared from 1,3-bis(1,3-dithian-2-yl)propane by a similar strategy or from a S(N) reaction of 1,3-dihalopropanes with 2-trialkylsilyl-2-lithio- 1,3dithiane and deprotection. The method allows efficient preparation of symmetrical as well as unsymmetrical bis(silylated) heterocycles.