223389-51-3

Usage

Uses

Used in Pharmaceutical Industry:
R-2,2'-bis(methoxymethoxy)-[1,1'-Binaphthalene]-3,3'-dicarboxaldehyde is utilized as a chiral building block for the synthesis of chiral pharmaceuticals. Its unique properties enable the creation of complex molecular structures with high selectivity, which is essential for developing new drugs with improved efficacy and reduced side effects.
Used in Agrochemical Industry:
In the agrochemical sector, R-2,2'-bis(methoxymethoxy)-[1,1'-Binaphthalene]-3,3'-dicarboxaldehyde is employed as a key intermediate in the production of chiral agrochemicals and fine chemicals. Its ability to enhance the selectivity and efficiency of chemical reactions contributes to the development of more effective and environmentally friendly agrochemical products.
Used in Organic Synthesis:
R-2,2'-bis(methoxymethoxy)-[1,1'-Binaphthalene]-3,3'-dicarboxaldehyde is used as a chiral ligand in various catalytic reactions, facilitating the synthesis of enantiomerically pure compounds. This is particularly important in organic synthesis, where the ability to produce specific enantiomers can significantly impact the biological activity and safety of the resulting compounds.
Used in Research and Development:
Due to its high efficiency in asymmetric synthesis, R-2,2'-bis(methoxymethoxy)-[1,1'-Binaphthalene]-3,3'-dicarboxaldehyde is a valuable tool for researchers and chemists in the development of new drugs and chemicals. Its unique properties allow for the exploration of novel synthetic pathways and the creation of innovative molecular structures with potential applications in various industries.

Upstream product

• 173831-50-0 rac-2,2'-bis-(methoxymethoxy)-1,1'-binaphthalene 
• 68-12-2 N,N-dimethyl-formamide 
• 109-72-8 n-butyllithium 
• 602-09-5 1,1'-bi-2-naphthol 

Downstream Products

• 141779-46-6 2,2’-dihydroxy-[1,1’-binaphthalene]-3,3’-dicarbaldehyde 

Relevant academic research and scientific papers

ESIPT-based ratiometric probe for Zn2+ detection based on BINOL framework

A ratiometric BINOL-based fluorescent probe for Zn2+ detection was rationally designed and synthesized. Based on the excited-state intramolecular proton transfer (ESIPT) mechanisms, the probe exhibited a significant variation on emission wavele

Strong Aggregation-Induced CPL Response Promoted by Chiral Emissive Nematic Liquid Crystals (N*-LCs)

In this paper we designed a kind of aggregation-induced emission (AIE) chiral fluorescence emitters (R/S-BINOL-CN enantiomers) in the aggregate state. Chiral emissive nematic liquid crystals (N*-LCs) prepared by doping this kind of AIE-active R/S-BINOL-CN enantiomers into a common achiral nematic liquid crystal (N-LC, E7) can self-assemble as the regularly planar Grandjean texture leading to high luminescence dissymmetry factor (glum) of aggregation-induced circularly polarized luminescence (AI-CPL) signal up to 0.41, which can be attributed to dipolar interactions from polar cyano groups and π–π interactions between binaphthyl moiety of the dopant R/S-BINOL-CN and biphenyl group of the host molecules (E7).

Compound boranil based on bi bisnaphthol of the framework and its preparation and use

The invention provides a series of Boranil compounds based on 1,1'-binaphthol parents, a preparation method of the compounds, and application of the compounds on detection of fluorine ions. The compounds meet one of the following general formulas, X is on

Self-assembly from metal-organic vesicles to globular networks: Metallogel-mediated phenylation of indole with phenyl boronic acid

Self-assembly of the conformationally flexible bismethylimidazolyl ligands with Pd(OAc)2 is described. Depending on whether the ligands provide the hydrogen bonding donor, a switching of metal-organic vesicles to globular networks gelating solvents is achieved. The metallogels exhibit catalytic activity for the cross-coupling of indole with phenyl boronic acid.

Chiral Ti(IV) complexes of hexadentate Schiff bases as precatalysts for aldehyde allylation: unusual additive effect of trimethylsilyl chloride

Chiral dinuclear titanium(IV) complexes have been found to be more effective catalysts for the asymmetric allylation of p-nitrobenzaldehyde than their mononuclear analogues. The addition of trimethylsilyl chloride to the reaction mixture decreases the rate of the background reaction and increases the yield of the reaction catalysed by the dinuclear complex.