22346-75-4Relevant academic research and scientific papers
Oxidation of N-heterocycles by H2O2 catalyzed by a Mn-porphyrin: An easy access to N-oxides under mild conditions
Thellend,Battioni,Sanderson,Mansuy
, p. 1387 - 1388 (2007/10/03)
A variety of N-heteroaromatic compounds were converted into their corresponding N-oxides with good yields and with high chemoselectivity in tile presence of hydrogen peroxide as oxygen donor and a catalytic amount of Mn-porphyrin. The scope and limitation of this method are discussed.
FURTHER FUNCTIONAL GROUP OXIDATIONS USING SODIUM PERBORATE
McKillop, Alexander,Kemp, Duncan
, p. 3299 - 3306 (2007/10/02)
Sodium perborate in acetic acid is an effective reagent for the oxidation of aromatic aldehydes to carboxylic acids, iodoarenes to (diacetoxyiodo)arenes, azines to N-oxides, and various types of sulfur heterocycles to S,S-dioxides.Nitriles are unaffected by the reagent in acetic acid, but undergo smooth hydration to amides when aqueous methanol is employed as solvent.
