223510-73-4

Basic information

• Product Name: (R)-(+)-1-phenyl-3-(2-naphthoxy)-1-butene
• Synonyms: (R)-(+)-1-phenyl-3-(2-naphthoxy)-1-butene
• CAS NO: 223510-73-4
• Molecular Weight: 274.362
• Mol File: 223510-73-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (R)-(+)-1-phenyl-3-(2-naphthoxy)-1-butene(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-(+)-1-phenyl-3-(2-naphthoxy)-1-butene(223510-73-4)
• EPA Substance Registry System: (R)-(+)-1-phenyl-3-(2-naphthoxy)-1-butene(223510-73-4)

Safety Data

• Hazardous Substances Data: 223510-73-4(Hazardous Substances Data)

Upstream product

• 115340-38-0 methyl (R)-[(E)-1-methyl-3-phenyl-2-propenyl] carbonate 
• 135-19-3 β-naphthol 

Relevant articles and documents

Molybdenum(II)-catalyzed allylation of electron-rich aromatics and heteroaromatics

The stable, readily available molybdenum(II) complexes [Mo(CO)4Br2]2 (B) and Mo(CO)3(MeCN)2-(SnCl3)Cl (C) have been found to catalyze C-C bond- forming allylic substitution with electronrich aromatics (e.g., 15 + PhOMe → 62) and heteroaromatics (e.g., 15 + 36 → 88) as nucleophiles under mild conditions (room temperature, 30 min-3 h). Remarkable is the para-selectivity for anisole, whereas phenol tends to favor ortho-substitution in certain instances. Mechanistic and stereochemical experiments are indicative of Lewis-acid catalysis rather than a metal template-controlled process.