223519-93-5Relevant academic research and scientific papers
A Water Stable Magnesium MOF That Conducts Protons over 10-2 S cm-1
Ramaswamy, Padmini,Wong, Norman E.,Gelfand, Benjamin S.,Shimizu, George K. H.
, p. 7640 - 7643 (2015)
From the outset of the study of MOFs as proton conductors, both conductivity and hydrolytic robustness of the materials have needed to be improved. Here, we report a layered magnesium carboxyphosphonate framework, PCMOF10, that shows an extremely high pro
Uranyl Carboxyphosphonates Derived from Hydrothermal in Situ Ligand Reaction: Syntheses, Structures, and Computational Investigations
Wu, Dai,Bai, Xiaojing,Tian, Hong-Rui,Yang, Weiting,Li, Zewen,Huang, Qing,Du, Shiyu,Sun, Zhong-Ming
, p. 8617 - 8624 (2015)
(Chemical Equation Presented). Two uranyl carboxyphosphonates (H2dipy)[(UO2)3(H2O)2(H2DPTP)2]·2H2O (DPTP-U1) and (H2bbi)[(UO2)4(H2O)2(HDPTP)2] (DPTP-U2) [H6DPTP = 2,5-diphosphonoterephthalic acid, dipy = 4,4′-bipyridine, bbi = 1,1′-(1,4-butanediyl)bis(imidazole)] were synthesized under hydrothermal conditions. The carboxyphosphonate ligand was formed through the in situ oxidation of (2,5-dimethyl-1,4-phenylene)diphosphonic acid mediated by UO22+. Single-crystal X-ray diffraction analyses reveal that DPTP-U1 possesses uranyl carboxyphosphonate layers that are separated by protonated dipy cations. Whereas DPTP-U2 is in a three-dimensional framework structure with channels filled by protonated bbi cations. The computational investigations give an insight into the nature of bonding interactions between uranium(VI) and carboxyphosphonate ligand. The spectroscopic properties were also studied.
Preparation of phosphonoterephthalic acids via palladium-catalyzed coupling of aromatic iodoesters
Ivan, Nathaniel,Benin, Vladimir,Morgan, Alexander B.
supporting information, p. 1831 - 1836 (2013/05/22)
The current article reports in detail the preparation of two phosphonoterephthalic acids: 2-phosphonoterephthalic acid (1) and 2,5-diphosphonoterephthalic acid (2). Efficient, scalable syntheses have been developed for both compounds based on Pd-catalyzed
