223545-81-1

Basic information

• Product Name: benzyl O-(2-azido-3,4,6-tri-O-benzyl-2-deoxy-β-D-glucopyranosyl)-(1->6)-2,3,4-tri-O-benzyl-β-D-glucopyranoside
• CAS NO: 223545-81-1
• Molecular Weight: 998.185
• Mol File: 223545-81-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: benzyl O-(2-azido-3,4,6-tri-O-benzyl-2-deoxy-β-D-glucopyranosyl)-(1->6)-2,3,4-tri-O-benzyl-β-D-glucopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: benzyl O-(2-azido-3,4,6-tri-O-benzyl-2-deoxy-β-D-glucopyranosyl)-(1->6)-2,3,4-tri-O-benzyl-β-D-glucopyranoside(223545-81-1)
• EPA Substance Registry System: benzyl O-(2-azido-3,4,6-tri-O-benzyl-2-deoxy-β-D-glucopyranosyl)-(1->6)-2,3,4-tri-O-benzyl-β-D-glucopyranoside(223545-81-1)

Safety Data

• Hazardous Substances Data: 223545-81-1(Hazardous Substances Data)

Upstream product

• 2873-29-2 D-glucal triacetate 
• 100-44-7 benzyl chloride 
• 55628-54-1 3,4,6-tri-O-benzyl-D-glucal 
• 27851-29-2 benzyl 2,3,4-tri-O-benzyl-D-glucopyranoside 

Downstream Products

• 223546-34-7 benzyl O-(2-acetamio-3,4,6-tri-O-benzyl-2-deoxy-β-D-glucopyranosyl)-(1->6)-2,3,4-tri-O-benzyl-β-D-glucopyranoside 

Relevant articles and documents

Glycosylation using 2-azido-3,4,6-tri-O-benzyl-2-deoxy-D-glucose, - galactose, and -mannose with the aid of p-nitrobenzenesulfonyl chloride- silver trifluoromethanesulfonate-triethylamine system

This report describes a simple synthesis of 2-azido-3,4,6-tri-O-benzyl- 2-deoxy-D-glucopyranose. Glycosylation using this as well as 2-azido-3,4,6- tri-O-benzyl-2-deoxy-D-galactopyranose and -mannopyranose was achieved with the aid of a reagent system consisting of p-nitrobenzenesulfonyl chloride, silver trifluoromethanesulfonate, and triethylamine, and its modifications. O-(2-Acetamido-2-deoxy-β-D-glucopyranosyl)-(1 → 4)-O-α-D-mannopyranosyl- (1 → 4)-a-D-mannopyranose, the repeating unit of the main chain of the O- specific cell wall polysaccharide of E. coli 058 was synthesized.