223575-99-3Relevant articles and documents
Carbonates: Eco-friendly solvents for palladium-catalysed direct arylation of heteroaromatics
Dong, Jia Jia,Roger, Julien,Verrier, Cecile,Martin, Thibaut,Le Goff, Ronan,Hoarau, Christophe,Doucet, Henri
experimental part, p. 2053 - 2063 (2011/02/25)
The palladium-catalysed direct 2-, 4- or 5-arylation of a wide range of heteroaromatics with aryl halides proceed in moderate to good yields using the eco-friendly solvents carbonates. The best yields were obtained using benzoxazole or thiazole derivatives. The arylation of furan, thiophene, pyrrole, imidazole or isoxazole derivatives was found to require a more elevated reaction temperature. The Royal Society of Chemistry 2010.